期刊
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
卷 105, 期 6, 页码 3665-3688出版社
WILEY
DOI: 10.1111/jace.18413
关键词
CMAS; environmental barrier coatings (EBC); phase equilibria; reaction path; thermal barrier coatings (TBC)
资金
- IHI Turbine Materials Research Center at the University of California, Santa Barbara
- Office of Naval Research [N00014-19-1-2377, N68335-20-C-0472]
This study presents a protocol for selecting representative silicate compositions for comparative testing of gas turbine coating materials. The protocol involves converting compositions of engine deposits and naturally occurring siliceous debris into the five major oxides and further refining them using principal component analysis and k-means clustering. The process results in four classes of possible deposits with common chemical characteristics. Key thermophysical properties of these deposits are calculated and related to the glass network connectivity. Finally, the reactions of deposits from each class with typical thermal and environmental barrier oxides are compared, considering the composition variations within each deposit class.
A protocol for selecting representative silicate compositions for comparative testing of gas turbine coating materials is presented. It begins with a curated dataset of compositions of engine deposits and naturally occurring siliceous debris including volcanic ashes, sands, and dusts. The compositions are first reduced to the five major oxides-those of Ca, Mg, Fe, Al, and Si-and then distilled further using principal component analysis and k-means clustering. The process ultimately yields four classes of possible deposits with common chemical characteristics. Each class is represented by a composition centroid and a range in Ca:Si ratios. Key thermophysical properties of the possible deposits are calculated and related to the glass network connectivity, characterized by the Si:O ratio. Finally, deposits from each of these classes are compared in terms of their reactions with prototypical thermal and environmental barrier oxides, with due consideration of the effects of composition variations within each deposit class. The protocol is, in principle, adaptable to datasets compiled by OEMs and researchers in gas turbine coatings.
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