4.6 Article

Structural, optical, dielectric, and magnetic properties of Sr0.7La0.3Zn0.3Fe11.7-xAlxO19 hexaferrite synthesized by the solid-state reaction method

期刊

JOURNAL OF SOLID STATE CHEMISTRY
卷 306, 期 -, 页码 -

出版社

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2021.122766

关键词

M -type hexaferrite; Solid -state reaction method; Al substitution; Dielectric property; Magnetic properties

资金

  1. National Natural Science Foundation of China [51764045]
  2. Science and Technology Program of Baotou City of China [2019Z3004-5]
  3. Inner Mongolia Autonomous Region Science and Technology Plan Project [2021GG0438]
  4. Inner Mongolia Natural Science Foundation [2020MS05048, 2020BS05029]

向作者/读者索取更多资源

M-type Sr0.7La0.3Zn0.3Fe11.7-xAlxO19 hexaferrites were prepared using the conventional solid state reaction method, showing single magnetoplumbite phase with Al3+ entering the lattice. Different doping levels affected the magnetic, electrical, and structural properties of the hexaferrites.
M-type Sr0.7La0.3Zn0.3Fe11.7-xAlxO19 hexaferrites were prepared using the conventional solid state reaction method in 1240 degrees C. XRD spectras indicated that there was a single magnetoplumbite phase with no detection of other phases for all samples. FT-IR and Raman spectra proves the formation of lattice and structure of M-type hexagonal ferrite respectively, and by the shift of the peaks, we speculate that Al3+ entered the lattice. FE-SEM micrographs showed that the grains were platelet-like shapes, EDS indicates that all elements are pre-determined and no other elements are produced. The impedance analyzer found that all the dielectric parameters were optimized in different degrees under the corresponding doping amount, and the change was consistent with the characteristics of hexagonal ferrite magnetic materials. VSM finds that H-C increased rapidly to a maximum value of 4576.8 Oe at x = 1.5, which was similar to 96.4% increase in coercivity as compared to that of Sr(0.7)La(0.3)Z-n(0.3)Al(x)Fe(11.7-x)O(19) at x = 0.0.

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