期刊
JOURNAL OF SOLID STATE CHEMISTRY
卷 303, 期 -, 页码 -出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2021.122479
关键词
Li4Ti5O12 microspheres; Br doping; Anode materials; Electrochemical performance; Lithium-ion batteries
资金
- General projects of Chongqing Natural Science Foundation [cstc2020jcyj-msxmX0136]
- Fundamental Research Funds for the Central Universities [2021CDJQY-048]
- Chongqing science and technology project [cstc2018jszxcyzdx0087]
Doping Li4Ti5O12 microspheres with bromine can improve the rate performance and cyclic ability by increasing the relative content of Ti3+, which benefits the transmission of electrons and ions. Among the doped samples, 0.2Br-LTOS exhibits superior rate performance and cyclic ability, with a capacity retention ratio of about 87.8% after 1000 cycles at 10C.
Br-doping Li4Ti5O12 microspheres (LTOS) with micro-nano hierarchical structure are synthesized using cetyltrimethylammonium hydroxide-assisted hydrothermal and further calcination. The structure and morphology of the obtained Br-doping LTOS were characterized by X-ray diffraction, scanning electron microscopy and X-ray photoelectron spectroscopy. It is found that the spherical morphology and spinel-type microstructure of LTOS do not change after appropriate Br doping, but the relative content of Ti3+ increases, which are beneficial for the fast transmission of electronics and ions. Therefore, the rate performances of LTOS are evidently improved after Br doping. Among the doped samples, 0.2Br-LTOS delivers the superior rate performance and cyclic ability. Their specific capacities at 1C, 5C, 10C, 20C, 30C and 40C are 133, 127, 121, 114, 109 and 105 mAh.g(-1), respectively. Even at 50C and 60C, their specific capacities are still as high as 101 and 96 mAh.g(-1), respectively. Moreover, their capacity retention ratio is about 87.8% after 1000 cycles at 10C, which is higher than 76.5% of pure LTOS.
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