Enhancing the activity and durability of iridium electrocatalyst supported on boron carbide by tuning the chemical state of iridium for oxygen evolution reaction

The main challenge for the anode electrocatalyst in a polymer electrolyte membrane water electrolyzer (PEMWE) is to maintain activity and stability simultaneously under the corrosive environment. We report a highly active and durable iridium electrocatalyst supported on boron carbide for the oxygen evolution reaction. The physical and electrochemical properties of the catalyst are controlled by changing the synthetic reduction temperature from 30 degrees C to 100 degrees C. The prepared Ir/B4C-100 degrees C catalyst shows two times higher mass activity than Ir/(4)C30 degrees C, even outperforming two commercial catalysts. The improved activity can be correlated to the high concentration of Ir (III) and OH species on the surface and the well-dispersed iridium nanoparticles on the support. Controlling the reduction temperature is also found to enhance iridium stability by developing the interactions between iridium and B4C. These metal-support interactions inhibit the oxidative dissolution of Ir (III) and the aggregation of iridium species. Ir/B4C-100 degrees C also shows better single cell performance than those of two commercial catalysts when tested in a PEMWE. The cell with the synthesized catalyst of Ir/B4C-100 degrees C shows a current density of 1.98 A/cm(2) at 1.8 V, whereas those with two commercial catalysts exhibit values of 1.36 and 0.692 A/cm(2) at 1.8 V, respectively.

Automated summary

A highly active and durable iridium electrocatalyst supported on boron carbide has been developed for the oxygen evolution reaction in a polymer electrolyte membrane water electrolyzer, exhibiting superior performance compared to two commercial catalysts. Control of reduction temperature plays a key role in enhancing both activity and stability of the catalyst.