Negative electron affinity opens quantum well in MgO layers on Ag(100)

Epitaxial MgO films on Ag(100) were studied by photoelectron spectroscopy. From the low-energy part of the spectra we obtain a negative electron affinity of about -0.9 eV. Even though electrons in the lowest conduction band are not confined by a potential barrier at the surface, quantum-well resonances are observed. The dispersion of the conduction band is determined in good agreement with theoretical calculations. Aspects of observing image-potential states predicted by theory on MgO films are discussed.

Automated summary

Epitaxial MgO films on Ag(100) were investigated using photoelectron spectroscopy. Negative electron affinity of about -0.9 eV was obtained from the low-energy region of the spectra. Despite the absence of potential barrier on the surface, quantum-well resonances were observed in the lowest conduction band. The results of this study are in good agreement with theoretical calculations and provide insight into the observation of image-potential states on MgO films.