Interspersing CeOx Clusters to the Pt-TiO2 Interfaces for Catalytic Promotion of TiO2-Supported Pt Nanoparticles

We propose an interface-engineered oxide-supported Pt nanoparticle-based catalyst with improved low-temperature activity toward CO oxidation. By wet-impregnating 1 wt % Ce on TiO2, we synthesized hybrid oxide support of CeOx-TiO2, in which dense CeOx clusters formed on the surface of TiO2. Then, the Pt/CeOx-TiO2 catalyst was synthesized by impregnating 2 wt % Pt on the CeOx-TiO2 supporting oxide. Pt-CeOx-TiO2 triphase interfaces were eventually formed upon impregnation of Pt on CeOx-TiO2. The Pt-CeOx-TiO2 interfaces open up the interface-mediated Mars-van Krevelen CO oxidation pathway, thus providing additional interfacial reaction sites for CO oxidation. Consequently, the specific reaction rate of Pt/CeOx-TiO2 for CO oxidation was increased by 3.2 times compared with that of Pt/TiO2 at 140 degrees C. Our results demonstrate a widely applicable and straightforward method of catalytic activation of the interfaces between metal nanoparticles and supporting oxides, which enabled fine-tuning of the catalytic performance of oxide-supported metal nanoparticle classes of heterogeneous catalysts.

Automated summary

We proposed an interface-engineered oxide-supported Pt nanoparticle-based catalyst, which exhibited improved low-temperature activity toward CO oxidation. The CeOx-TiO2 hybrid oxide support was synthesized by wet-impregnating 1 wt % Ce on TiO2, and the Pt/CeOx-TiO2 catalyst was prepared by impregnating 2 wt % Pt on the CeOx-TiO2 support. The formation of Pt-CeOx-TiO2 interfaces opened up the interface-mediated Mars-van Krevelen CO oxidation pathway, leading to additional interfacial reaction sites for CO oxidation. The specific reaction rate of Pt/CeOx-TiO2 for CO oxidation was increased by 3.2 times compared with Pt/TiO2 at 140 degrees C.