期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 125, 期 43, 页码 24180-24188出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.1c07410
关键词
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资金
- National Natural Science Foundation of China [22071184]
- Zhejiang Provincial Natural Science Foundation of China [LY20B020014]
Two isoquinoline derivatives with different connecting units show distinct photophysical properties, with one exhibiting an aggregation-induced emission (AIE) phenomenon due to the presence of double bonds, and the other showing solvatochromic and dual-state emission properties with a single bond as the connecting unit. The study provides important insights into the impact of connecting units on the photophysical properties of fluorescent materials.
Two isoquinoline derivatives IQ-BIM and IQ-BM with a terminal malononitrile unit, in which the double bond and single bond are used as the connecting units, respectively, are obtained simultaneously by the reaction of an isoquinoline derivative with malononitrile in the presence of a catalytic amount of triethylamine. The different connecting units show an important effect on their photophysical properties. IQ-BIM with an acceptor-pi-acceptor structure exhibits an obvious aggregation-induced emission (AIE) phenomenon in the tetrahydrofuran-water mixed solvent owing to the restriction of intramolecular rotation but no obvious solvatochromic property, whereas IQ-BM with a donor-pi-acceptor structure shows obvious solvatochromic and dual-state emission properties, and its emissions in the mixtures are mainly dominated by the intramolecular charge transfer effect. This result indicates that the existence of double bonds is beneficial to the occurrence of the AIE phenomenon. Although both these compounds exhibit outstanding mechanofluorochromic (MFC) activities through the crystalline-to-amorphous transition, the red shift of the fluorescence spectrum of IQ-BIM is attributed to the increased molecular conjugation, whereas that of IQ-BM is due to the generation of the excimers induced by the pi-pi interactions. Moreover, the former displays a higher contrast MFC phenomenon than the latter due to the looser stacking arrangement. This work gives important reference values for understanding the influence of the connecting units on the photophysical properties of fluorescent materials.
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