4.6 Article

Separation of Metallic and Semiconducting Single-Wall Carbon Nanotubes Using Sodium Hyodeoxycholate Surfactant

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Summary: A method to separate SWCNTs by chiral angle through temperature control of a binary surfactant system was reported in this study, resulting in efficient separation of 11 single-chirality SWCNT species including multiple zigzag and near-zigzag species at a submilligram scale. Lowering the temperature induced selective adsorption and reorganization of the cosurfactants on SWCNTs with different chiral angles, amplifying their interaction difference with gel. This work is believed to be a significant step towards industrial separation of single-chirality zigzag and near-zigzag SWCNTs.

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