期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 959, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2021.122207
关键词
Heck reaction; Rhodium catalysis; Oxidative Heck; Heterogeneous; Homogeneous
资金
- Council of Scientific and Industrial Research (CSIR), New Delhi
- Department of Science and Technology (DST-New Delhi) under the DST-PURSE programme
This article provides a comprehensive review of rhodium-catalysed Heck type reactions, including oxidative, decyanative, desulfitative, decarbonylative Heck reactions, and even Heck type cyclizations, covering literature until 2021.
Heck coupling has emerged as a powerful tool for C -C bond construction in organic chemistry. Traditionally, Heck reactions were catalysed by Pd, however sufficient research is done on rhodium-catalysed Heck type reactions due to its high efficiency. A wide range of Heck type coupling including oxidative, decyanative, desulfitative, decarbonylative Heck reaction, and even Heck type cyclizations have been described so far. Herein, we summarize the first review giving an overview of rhodium-catalysed Heck type reactions covering literature until 2021.
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