期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 86, 期 22, 页码 16084-16094出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.1c01688
关键词
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资金
- CSIR
- SERB, DST, India [CRG/2020/006021]
- IISER Kolkata
The mild and efficient electrochemically driven synthetic route allows for the access of polysubstituted selenofuran derivatives through diselenide-promoted cyclization of homopropargyl alcohols, with up to 84% isolated yield. This methodology demonstrates good functional group compatibility and further conversion to valuable furan derivatives.
The current method represents an electrochemi-cally driven synthetic route to access polysubstituted selenofuran derivatives through the diselenide-promoted cyclization of homopropargyl alcohols. The tandem electro-oxidative trans-formation operates at ambient temperature and in the absence of an external oxidant. This mild and efficient methodology exhibits good functional group compatibility, providing a broad range of substrate scopes up to 84% isolated yield. Further conversion of the seleno-functionality afforded other valuable furan derivatives.
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