期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 86, 期 21, 页码 15743-15752出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.1c01775
关键词
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资金
- National Natural Science Foundation of China [21772195]
- Fundamental Research Funds for the Central Universities [DUT20RC5030]
A new strategy for cross-dehydrogenative C-C and C-P coupling reaction without the use of a photocatalyst has been developed. This method allows for the synthesis of various 1-substituted tetrahydroisoquinoline derivatives through visible-light direct excitation of substrates. The broad substrate scope demonstrates good synthetic versatility and practicality.
A new photocatalyst-free strategy for the cross-dehydrogenative C-C and C-P coupling reaction has been described. This protocol provides a concise method to synthesize various 1-substituted tetrahydroisoquinoline (THIQ) derivatives enabled by visible-light direct excitation of substrates without using any photocatalyst. Moreover, a wide substrate scope demonstrated good synthetic versatility and practicality.
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