期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 87, 期 5, 页码 3605-3612出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.1c03156
关键词
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资金
- National Natural Science Foundation of China [21772022, 22171124]
- Minjiang University [MJY21041]
- Fuzhou University
An oxidative copper-mediated double trifluorome-thylselenolation of terminal 2-alkynylanilines using [(bpy)-CuSeCF3](2) is reported, providing a moderately efficient and convenient approach to 2,3-bis(trifluoromethylseleno)indoles. Mechanistic studies show that a cascade sequence of oxidation, trifluoromethylselenolation, 5-endo-dig cyclization, and elimination is involved in this transformation.
An oxidative copper-mediated double trifluorome-thylselenolation of terminal 2-alkynylanilines using [(bpy)-CuSeCF3](2) is reported, providing a moderately efficient and convenient approach to 2,3-bis(trifluoromethylseleno)indoles. Mechanistic studies show that a cascade sequence of oxidation, trifluoromethylselenolation, 5-endo-dig cyclization, and elimination is involved in this transformation.
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