期刊
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
卷 88, 期 1, 页码 28-58出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20140261
关键词
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资金
- PRESTO, Japan Science and Technology Agency (JST)
- CREST project from the Ministry of Education, Culture, Sports, Science and Technology (MEXT) [17750120, 24685022, 20350061, 20651025, 23651089]
- Japan Society for the Promotion of Science (JSPS)
- India-Japan Cooperative Science Programme (IJCSP)
- Hattori Hokokai Foundation
- Asahi Glass Foundation
- Kao Foundation for Arts and Sciences
- Futaba Electronics Memorial Foundation
- Tokuyama Science Foundation
- Shorai Foundation for Science and Technology
- Iketani Science Technology Foundation
- Canon Co., LTD
- Japan Association for Chemical Innovation
- Izumi Science and Technology Foundation
- Sumitomo Foundation
- Sekisui Chemical Co., LTD.
- Grants-in-Aid for Scientific Research [20651025, 20350061, 23651089, 17750120, 24685022, 26102010] Funding Source: KAKEN
As details of exciting photonic and electronic properties arising from self-assembled functional dyes and related pi-conjugated molecules become clearer, strategies for control of short and long-range chromophore chromophore orientations, regulation of pi-pi stacking arrangements, construction of self-organized nano-to-microscale architectures, diversification of materials properties, analysis of self-assembly pathways, and impartment of stimuli-responsive properties, are all becoming important issues in the research area of organic functional materials. This article focuses on the supramolecular assemblies of dyes and related pi-conjugated systems whose organization processes are rationally controlled by complementary multiple hydrogen bonding (CMHB) interactions between melamine and barbituric acid/cyanurate functional units. The article includes an overview of the construction principle of such systems, but special attention is focused on the work carried out in the authors's group (since 2002) using azobenzene, diarylethene, merocyanine, perylene bisimide dyes, and pi-conjugated oligomers including oligo(p-phenylenevinylene), oligo(p-phenyleneethynylene), and oligothiophenes. The design principles discussed in this account could open up new avenues to novel functional aspect and application of functional dyes and small-molecular pi-conjugated systems.
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