期刊
JOURNAL OF MOLECULAR STRUCTURE
卷 1246, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.molstruc.2021.131150
关键词
PNBTAN; Palladium; Liquid-liquid microextraction; UV-VIS spectrometry
资金
- International Visegrad Fund [51910482]
- Scientific Grant Agency VEGA of the Ministry of Educa-tion of the Slovak Republic
- Slovak Academy of Sciences [1/0220/21]
A new method for determining palladium by dispersive liquid-liquid microextraction preconcentration with UV-VIS spectrometry detection has been developed. The method utilizes PNBTAN as a chelating agent and traditional organic solvents, achieving a low limit of detection and good linearity under optimal conditions.
A new method for the determination of palladium has been developed based on the dispersive liquid-liquid microextraction preconcentration with UV-VIS spectrometry detection. In the proposed approach, 1-[(5-(3-nitrobenzyl)-1,3-thiazol-2-yl)diazenyl]naphthalen-2-ol (PNBTAN) was used as a new chelating agent, and methyl isobutyl ketone and ethanol were selected as extraction and dispersive solvents. The limit of detection (LOD), based on the signal-to-noise (S/N) ratio of 3, was 0.093 mu g mL(-1). Linearity was observed over the range of 0.24-1.437 mu g mL(-1) with the correlation coefficient (R ) of 0.9993. The developed method has been successfully tested and applied to the determination of trace amounts of palladium in real objects. Analytical properties of PNBTAN and its complexes with palladium were investigated by theoretical calculations and experimental spectrophotometric method. Electron localization function, Fukui function, and molecular electrostatic potential isosurfaces were analyzed as reactivity descriptors for the explanation of the PNBTAN chelation ability. DFT analysis of eleven possible structures of the Pd:PNBTAN (1:2) complex has established the preferred formation of six-membered-O-Pd-N = N containing cycles. According to the TD-DFT calculations, the experimentally observed bands at 747 and 680 nm in the UV-VIS spectrum of the Pd:PNBTAN (1:2) complex were assigned to the HOMO -> LUMO and HOMO -> LUMO + 1 electron transitions, respectively. (C) 2021 Elsevier B.V. All rights reserved.
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