期刊
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
卷 88, 期 10, 页码 1357-1377出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20150151
关键词
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资金
- Ministry of Education, Culture, Sports, Science, and Technology, Japan
- SORST
- PRESTO
- CREST from Japan Science and Technology Agency
- Grants-in-Aid for Scientific Research [26288093] Funding Source: KAKEN
Boron, a group 13 element, has several characteristic structural and electronic features: 1) trivalent boron compounds usually adopt a trigonal planar geometry; 2) due to the presence of a vacant p-orbital, effective orbital interaction with pi-conjugated compounds is possible; 3) the presence of a vacant p-orbital is furthermore responsible for high Lewis acidity; 4) the boryl group acts as a pi-electron-accepting group particularly in the excited state. The consequent exploitation of these characteristic features of boron in the molecular design enables us to produce sophisticated pi-functional materials with attractive photophysical and electronic properties. This account article illustrates our systematic studies on the molecular design and the development of functional pi-electron materials using boron as a key element.
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