期刊
JOURNAL OF MOLECULAR LIQUIDS
卷 353, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.molliq.2022.118694
关键词
Phase equilibrium; Density; Volume properties; Molten salts; Lanthanides; Fluorides
资金
- Slovak Research and Development Agency [APVV-19-0270]
- Slovak Grant Agency [VEGA 2/0024/20]
Phase equilibria and density of molten systems (LiF-MgF2)(eut)-LnF(3) (Ln = Sm, Gd, Nd) were investigated using thermal analysis and X-ray powder diffraction. The study revealed an increasing concentration dependency in density and molar volume for the investigated molten systems.
Phase equilibria and density of the molten systems (LiF-MgF2)(eut)-LnF(3) (Ln = Sm, Gd, Nd) were determined by means of thermal analysis and Archimedean method of hydrostatic weighing as well-established methods for the investigation of the molten salts. Solidified samples after the thermal analysis were analysed by XRD analysis and phase analysis (qualitative and quantitative) of these samples was performed by means of X-ray powder diffraction (XRPD) for the identification of unidentified phases. The investigation of the volume properties showed the increasing tendency of concentration dependencies of density and molar volume and volume contraction for all three investigated molten systems. (C)& nbsp;2022 Elsevier B.V. All rights reserved.
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