期刊
JOURNAL OF MOLECULAR LIQUIDS
卷 345, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.molliq.2021.117901
关键词
Phenolic compounds; Bronsted acid-Lewis base coordination; Functionalized ionic liquid; Intermolecular insight; Extractive separation
资金
- National Natural Science Foundation of China [21978155, 21908131]
- Natural Science Foundation of Shandong Province [ZR2019BB066]
- Open Project of Qingdao University of Science and Technology Chemistry Department [QUSTHX202009]
The study successfully developed a simple and easy prepared carboxyl functionalized ionic liquid for effective separation of phenolic compounds from oil mixtures. The extraction efficiency was measured under different conditions and showed good results for m-cresol, o-cresol, p-cresol, and phenol, with the ionic liquid being reusable after experimentation.
Phenolic compounds (PCs) are value-added materials in producing medicines and disinfectants, which were enriched in the coal tar oils. However, the commonly industrial applied methods exposed several environmental concerns. Thus, the utilization separation of PCs using a green and sustainable technology present both commercial and biological value. In the present work, a type of simple and easy prepared carboxyl functionalized ionic liquid, 1-carboxyethyl-3-methylimidazolium nitrate ([CeMIM][NO3]), was designed based on the Bronsted/Lewis coordination theory and prepared to effective separation of PCs from the oil mixtures, taking m-cresol as the example. The total nonbonded interaction energy (E-total), spatial distribution function (SDF) and averaged noncovalent interaction (aNCl) were calculated to reveal that the formed H-bonds were enhanced by the functional group of the adopted IL. Moreover, FT-IR was also performed to prove the H-bonds interaction and acid-base coordination with the IL. Afterwards, the performance was explored by measuring the variation of the extraction efficiency (E) under different separation conditions such as separation temperature (ST), the mass ratio of IL to model oil (m(II)/m(oil)), and extraction time (ET). Meanwhile, the separation performance of [CeMIM][NO3] on other phenols was also investigated and followed by the regeneration of [CeMIM][NO3]. The E values are 98.77 % for m-cresol, 97.65 % for o-cresol, 98.03 % for p-cresol and 98.14 % for phenol with m(II)/m(oil) = 1:5 and extraction time 30 min at 298.15 K. (C) 2021 Elsevier B.V. All rights reserved.
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