期刊
JOURNAL OF MEMBRANE SCIENCE
卷 642, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.memsci.2021.119976
关键词
Forward osmosis; Polyethylene; Tannic acid; Coordination; Thin-film composite membrane
资金
- Fundamental Research Funds for the Central Universities [201964020]
- National Natural Science Foundation of China [U1607124]
A novel thin-film composite (TFC) membrane for forward osmosis (FO) was fabricated by introducing a tannic acid (TA)-Fe3+ interlayer on a polydopamine (PDA)-modified polyethylene (PE) support. The unique wormlike morphology of the polyamide (PA) layer in the membrane increased water flux and reduced salt flux, overcoming the trade-off between permeability and selectivity. The TA-Fe3+ interlayer enhanced the adhesion strength between PA layer and PDA-modified PE support, resulting in excellent stability of the TFC membrane for FO applications.
Polyethylene (PE) has recently gained attention as an advantageous support material in forward osmosis (FO) owing to its low structural parameters. A novel thin-film composite (TFC) membrane for FO was fabricated by introducing a tannic acid (TA)-Fe3+ interlayer on a polydopamine (PDA)-modified PE support via interfacial polymerization. The TA-Fe3+ interlayer influenced the diffusion of m-phenylenediamine, causing a unique wormlike morphology of the polyamide (PA) layer, distinct from the traditional ridge and valley morphology. Wormlike structures provided more permeation sites and improved the water flux (71.2 L.m(-2).h(-1)). Furthermore, the TA-Fe3+ interlayer prevented some salt molecules from passing through and resulted in a low specific salt flux (0.03 g.L-1). The TA-Fe3+ interlayer was the key to overcoming the trade-off between permeability and selectivity. It functioned as a bridge connecting the PA layer and the PDA-modified PE support through chemical bonding, and the adhesion strength between PA layer and PDA-modified PE support was enhanced. This resulted in the excellent stability of the obtained TFC membrane. This study presents a new method for the design of a TFC membrane with excellent perm-selectivity and manipulatable morphologies of the PA layer for FO applications.
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