期刊
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
卷 88, 期 1, 页码 146-148出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20140250
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资金
- Grants-in-Aid for Scientific Research [24510298, 24550055, 26410121, 15K05429] Funding Source: KAKEN
Construction of macrocyclic trienes by diene-ene RCM of tetraenes was examined. In the reactions, macrocyclic trienes were obtained as a mixture of two isomers with E,Z-configured 1,3-diene moiety. The formation of two isomers can be understandable by the E-Z isomerization of the initially generated ruthenium alkenyl carbene intermediate.
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