4.6 Article

The thermal conductivity and tolerance factor modulated ferroelectric thermal stability of Ba0.955La0.03TiO3 relaxor ferroelectric

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SPRINGER
DOI: 10.1007/s10854-022-07911-9

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  1. National Natural Science Foundation of China [51604087, 11574057, 11904056, 12172093]
  2. Science and Technology Program of Guangdong Province of China [2017A010104022]
  3. Guangdong Basic and Applied Basic Research Foundation [2021A1515012607]

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Ba0.955La0.03TiO3-doped Zr ferroelectric ceramics were prepared by solid-state reaction method, and the experimental results confirmed the adjustable thermal stability of these ceramics. Various characterization methods demonstrated the good crystallization and electrical properties of the ceramics.
Based on the design from the view of the Goldschmidt tolerance factor, Ba0.955La0.03TiO3-doped Zr ferroelectric ceramics were prepared by solid-state reaction method. The experimental results show that our hypothesis does adjust the thermal stability Ba0.955La0.03TiO3 ferroelectric ceramics. The findings can be supported by the actual results of the following characterization methods. Room-temperature X-ray diffraction and field emission scanning microscopy demonstrate that the crystallization of these ceramics is good. The essential dielectric properties, electrical conductivity, impedance spectroscopy, and electrical modulus of ceramics were measured. Besides, impedance spectroscopy and electrical modulus spectrum indicated that the high-temperature dielectric relaxation behavior is related to the oxygen vacancies.

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