4.6 Article

Flowerlike Bi2O2(OH)NO3/BiOCl nanocomposite with enhance photodegradation activity under simulated sunlight irradiation

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SPRINGER
DOI: 10.1007/s10854-021-07291-6

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  1. National Natural Science Foundation of China [21406058, 51775183]
  2. Hunan Provincial Natural Science Fund of China [2018JJ2125, 2021JJ30237, 2021JJ30259]

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A unique flowerlike Bi2O2(OH)NO3/BiOCl nanocomposite was synthesized and characterized, showing improved photocatalytic activity attributed to enhanced photogenerated electron-hole separation and synergistic effect between components. The 9% BON-BOC exhibited the best photodegradation activity with 92% degradation in 100 min, and the photocatalytic mechanism was investigated in detail.
A unique flowerlike Bi2O2(OH)NO3/BiOCl nanocomposite was successfully synthesized and characterized by XRD, SEM, TEM, N-2 adsorption-desorption and XPS. The Bi2O2(OH)NO3/BiOCl nanocomposites display improved photocatalytic activity than pure Bi2O2(OH)NO3 and BiOCl. Spectroscopic results and photoelectrochemical analysis revealed that the improved photocatalytic activity is mainly attributed to the enhanced photogenerated electron-hole separation in Bi2O2(OH)NO3/BiOCl heterostructure and synergistic effect between two component. Among them, 9% BON-BOC exhibits the best photodegradation activity of dye solution with 92% of degradation in 100 min. In addition, the photocatalytic mechanism were also investigated in detail.

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