A visibly transparent radiative cooling film with self-cleaning function produced by solution processing

Daylighting structures, including solar cells and building windows, utilize sunlight whilst suffering from undesired solar heat and outdoor dust contamination. A radiative cooling system that is transparent to sunlight and has a superhydrophobic surface would cool and clean the daylighting structures in a sustainable manner. However, the majority of the current daytime radiative cooling systems were designed to fully reflect the incident sunlight to maximize the cooling power. In this work, we optimized both the sunlight transmission and infrared thermal irradiation by modeling the size-dependent scattering and absorption of light by SiO2 spheres embedded in a polymer matrix, we found that the use of nanospheres (20 nm) enabled both high sunlight transmittance (> 90%) and infrared emissivity (similar to 0.85). This theoretical prediction was confirmed by experimental measurements of a solution-processed nanocomposite film. When coated on a solar cell, the as-prepared film not only preserved the power conversion efficiency of the cell (14.71%, uncoated cell has an efficiency of 14.79%) but also radiatively cooled the cell by up to 5 degrees C under direct sunlight. This reduction of the operating temperature of the solar cell further enhanced its electrical power output, evidenced by an increase in the equilibrium temperature of the LED load by about 14 degrees C. The nanoscale textured surface formed by the nanospheres further led to superhydrophobicity and thus excellent self-cleaning performance (efficient removal of dust by wind and/or water droplets). (C) 2021 Published by Elsevier Ltd on behalf of Chinese Society for Metals.

Automated summary

Daylighting structures face issues with solar heat and dust contamination. A radiative cooling system utilizing nanospheres embedded in a polymer matrix was found to efficiently cool and clean the structures while maintaining high sunlight transmittance and infrared emissivity. The nanocomposite film not only preserved the efficiency of solar cells but also enhanced their electrical power output by reducing operating temperatures and providing self-cleaning properties.