Microstructure controlle d synthesis of Ni, N-codope d CoP/carbon fiber hybrids with improving reaction kinetics for superior sodium storage

Transition-metal phosphides (TMPs)-based hybrid structure have received considerable attention for efficient sodium storage owing to their high capacity and decent reversibility. However, the volume expansion & the poor electronic conductivity of TMPs, the poor-rate capability, and fast capacity decay greatly hinder its practical application. To address these issues, a low-cost and facile strategy for the synthesis of Ni, N-codoped graphitized carbon (C) and cobalt phosphide (CoP) embedded in carbon fiber (Ni-CoP@C-N subset of CF) as self-supporting anode material is demonstrated for the first time. The graphitized carbon and carbon fiber improve the electrical conductivity and inhibit the volume expansion issues. In addition to that, the microporous structure, and ultrasmall sized Ni-CoP offer a high surface area for electrolyte wettability, short Na-ion diffusion path and fast charge transport kinetics. As a result, outstanding electrochemical performance with an average capacity decay of 0.04% cycle(-1) at 20 00 mA g(-1), an excellent rate capability of 270 mAh g(-1) @2000 mA g(-1) and a high energy density of similar to 231.1 Wh kg(-1) is achieved with binder-free self-supporting anode material. This work shows a potential for designing binder-free and high energy density sodium-ion batteries. (C) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

Automated summary

The research presents a new synthesis strategy for a novel self-supporting anode material, demonstrating improved sodium storage performance by combining nickel, nitrogen co-doped graphitized carbon and cobalt phosphide embedded in carbon fiber, addressing issues such as volume expansion and poor electronic conductivity of transition-metal phosphides, achieving outstanding electrochemical performance.