Superhigh co-adsorption of tetracycline and copper by the ultrathin g-C3N4 modified graphene oxide hydrogels

Development of economic and efficient absorbent for the simultaneous removal of antibiotics and heavy metals is needed. In this study, a three-dimensional porous ultrathin g-C3N4 (UCN) /graphene oxide (GO) hydrogel (UCNGH) was prepared by co-assembling of UCN and GO nanosheets via the facile hydrothermal reaction. Characterizations indicated that the addition of UCN significantly decreased the reduction of C=O and O-C=O related groups of GO during the hydrothermal reaction and introduced amine groups on UCN-GH. The UCN-GH exhibited excellent ability on the co-removal of Cu(II) (q(max) = 2.0-2.5 mmol g(-1)) and tetracycline (TC) (q(max) = 1.2-3.0 mmol g(-1)) from water. The adsorption capacities were increased as UCN mass ratio increasing. The mutual effects between Cu(II) and TC were examined through adsorption kinetics and isotherm models. Characterizations and computational chemistry analysis indicated that Cu(II) is apt to coordinate with the amine groups on UCN than with oxygen groups on GO, which accounts for the enhanced adsorption ability of UCN-GH. In the binary system, Cu(II) acts as a bridge between TC and UCN-GH enhanced the removal of TC. The effects of pH and regular salt ions on the removal of Cu(II)/TC were examined. Moreover, the prepared UCN-GH also showed comparable co-adsorption capacities in practical water/wastewater.

Automated summary

A three-dimensional porous ultrathin g-C3N4/graphene oxide hydrogel was prepared via hydrothermal reaction, showing excellent ability in co-removal of Cu(II) and tetracycline from water. In the binary system, Cu(II) acted as a bridge between tetracycline and UCNGH, enhancing tetracycline removal.