One-pot green synthesis of graphene oxide/MnO2/polyaniline nanocomposites applied in aqueous and neutral supercapacitors and sensors

Different binary and ternary nanocomposites among graphene oxide (GO), manganese dioxide (MnO2) nanoparticles and polyaniline (Pani) were synthesized in aqueous medium and room temperature using KMnO4 as oxidizing agent for aniline and precursor for MnO2 in the presence of GO. The ratio between the constituents was directly dependent on the HCl concentration and aniline amount used in the synthesis. Indeed, the lower the acid concentration, the greater the MnO2 ratio (similar to 65% using 0.01 mol L-1 HCl). The globular morphology of Pani presented higher degrees of polymerization and larger size of spheres according to the increase of acid concentration. MnO2 nanoparticles exhibited a birnessite structure with a mean size of similar to 1 nm well spread throughout the polymer matrix. The multifunctionality of the nanocomposites was evaluated in neutral aqueous solutions as supercapacitors and electrochemical sensors to H2O2. In both cases, the nanocomposites with the highest MnO2 proportion exhibited the best performances, reaching capacitances as high as similar to 150 F g(-1) with 68.2% of stability under 500 charge-discharge cycles and limit of detection as low as 3.03 +/- 0.22 mu mol L-1 for the ternary nanocomposites.

Automated summary

Different binary and ternary nanocomposites were synthesized among graphene oxide, manganese dioxide nanoparticles, and polyaniline using KMnO4 as an oxidizing agent and precursor for MnO2. The ratio of constituents depended on HCl concentration and aniline amount. The nanocomposites with higher MnO2 proportion showed the best performance as supercapacitors and electrochemical sensors, reaching capacitances of up to 150 F g(-1) and low detection limits for H2O2.