期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 898, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2021.115607
关键词
Nanosheets; Flower-like structure; Copper sulfide; Microwave-assisted synthesis; Sodium-ion batteries
资金
- Fundamental Research Funds for the Central Universities [N172302001, N172304044, N182304015, N182304017, N182306001]
- National Natural Science Foundation of China [51674068, 51771046, 51774002, 51874079, 51871046, 51704064, 51804035, 11775226]
- Natural Science Foundation of Hebei Province [E2018501091, E2020501001]
- Natural Science Foundation of Liaoning Province [2019-MS-110]
- Training Foundation for Scientific Research of Talents Project, Hebei Province [A2016005004]
- Qin-huangdao City University student of Science and Technology Innovation and Entrepreneurship Project [PZB1810008T-46, PZB1810008T-14]
The study designed a camellia-like CuS superstructure to enhance cycling stability and rate performance in sodium-ion batteries, demonstrating stable high capacity and long cycle life.
Layered copper sulfide (CuS) has immense commercial application potential in sodium-ion batteries (SIBs) due to its high capacity, diverse structures, and controllable synthetic methods. Despite these advantages, due to the large volume changes and soluble polysulfide intermediates based on the conversion reaction, it is a huge challenge for CuS electrodes to maintain high-rate performance and long-term cycle stability. Herein, a camellia-like CuS superstructure is designed and synthesized to improve cycling stability and rate performance. The cycling stability reflects in a stable capacity of 347.1 mAh g(-1) can still be retained at 0.1 A g(-1) after 100 cycles, and even after 1000 cycles at 5.0 A g(-1) without decay. The excellent rate performance is embodied in the capacity of 352.4 and 255.7 mAh g(-1) at 0.05 and 5.0 A g(-1), respectively. This work provides a feasible route to develop CuS anode material of SIBs with remarkable sodium storage performance.
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