期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 605, 期 -, 页码 863-870出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2021.07.123
关键词
Colloidal squares; Cylindrical surface; Self-assembly; Curvature; Entropy
资金
- National Natural Science Foundation of China [21573159, 11874277, 11704276, 11947242]
- National Science Foundation of Tianjin [19JCQNJC14900]
- National Science Foundation (USA) [NSF-DMR-1905347]
The study investigates the self-assembly of Brownian colloids on curved surfaces, demonstrating the significant influence of curvature on the phase behavior. Experimental findings reveal phase diagram changes with curvature, while simulations illustrate helical structures formed by square platelets packing on cylinders. These results highlight the control over particle self-assembly through curvature and depletion attraction-induced orientational confinement.
Hypothesis: We hypothesize that curved surfaces, including cylindrical surfaces, which go beyond prior experiments using flat surfaces, can significantly influence and alter the phase behavior and self-assembly of dense two-dimensional systems of Brownian colloids. Experiments: Here, we report a first experimental study regarding the self-assembly of Brownian square platelets with an edge length L = 2.3 mu m on cylindrical surfaces having different curvatures; these plate-lets are subjected to a depletion attraction in order to form a monolayer above the cylindrical surface, yet have nearly hard interactions within the monolayer. Simulations are also performed to confirm and explain the experimental observations. Findings: Phase diagrams as a function of curvature are determined experimentally. Interestingly, hexagonal rotator crystal structures are observed for tubes having radii > 10.9L, but a tetratic phase is seen instead for the 10.9L tube at the corresponding platelet area fractions. We show that this transition is caused by the curvature-induced orientation-dependence of the depletion attraction between the squares and the underlying cylindrical surface. Brownian dynamics simulation results confirm the experimental observations and also illustrate helical structures formed by squares packing on cylinders. Our results demonstrate a way towards control over the self-assembly of anisotropic particles through curvature and depletion-attraction-induced orientational confinement. (C) 2021 The Author(s). Published by Elsevier Inc.
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