期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 602, 期 -, 页码 367-375出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2021.06.040
关键词
Nanocatalysts; Bimetallic nanoparticles; Microemulsion; One-pot method
资金
- Conselleria de Cultura, Educacion e Ordenacion Universitaria, Xunta de Galicia, Spain [ED431C 2017/22, AEMAT ED431E2018/08]
- Universidade de Vigo/CISUG
- la Caixa Foundation [LCF/PR/PR12/11070003]
By conducting computer simulation studies, the mechanisms of surface composition formation of bimetallic nanoparticles under different synthesis conditions can be understood. The study results provide specific guidelines for experimental synthesis of bimetallic nanoparticles with tailored surfaces.
The enhancement of catalysts efficiency of bimetallic nanoparticles depends on the ability to exert con-trol over surface composition. However, results relating surface composition and feeding solution of bimetallic nanoparticles synthesized in microemulsions are controversial and apparently contradictory. In order to comprehend how the resulting surface can be modified under different synthesis conditions and for different pairs of metals, a computer simulation study was carried out. The resulting surface com-positions are explained based on the relative rates of deposition of the two metals, which depend on the particular metal pair, the concentration of reactants and the microemulsion composition. This study pro -vides a satisfactory understanding of experimental results and allows us to identify the main factors affecting the nanoparticle's surface composition. Consequently, concrete and practical guidelines can be established to facilitate the experimental synthesis of bimetallic nanoparticles with tailored surfaces. (c) 2021 The Authors. Published by Elsevier Inc. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
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