期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 607, 期 -, 页码 2010-2018出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2021.09.189
关键词
Flexible humidity sensor; Multifunction; Non-contact; Co-metal organic frameworks; Phytic acid
资金
- Natural Science Foundation of Hebei Province [F2020202050]
- National Natural Science Foundation of China [52104189, 62004059, 11632004, U1864208]
- Key Program for International Science and Technology Cooperation Projects of the Ministry of Science and Technology of China [2016YFE0125900]
- National Science and Technology Major Project [2017-VII-0011-0106]
- Science and Technology Planning Project of Tianjin [20ZYJDJC00030]
- Key Program of Research and Development of Hebei Province [202030507040009]
- Fund for Innovative Research Groups of Natural Science Foundation of Hebei Province [A2020202002]
- Key Project of Natural Science Foundation of Tianjin [S20ZDF077]
The research introduces a flexible, noncontact and multifunctional humidity sensor based on Co-metal organic frameworks (Co-MOF) nanosheets modified with phytic acid (PA). The sensor exhibits enhanced sensitivity and broad response range within 23-95% RH compared to Co-MOF-based sensors. It shows great flexibility and humidity sensing properties, enabling multifunctional applications in real-time facial respiration monitoring, skin humidity perception, cosmetic moisturizing evaluation, and fruit freshness testing.
The development of high-performance humidity sensors is of great significance to explore their practical applications in the fields of environment, energy saving and safety monitoring. Herein, a flexible, noncontact and multifunctional humidity sensor based on two-dimensional Co-metal organic frameworks (Co-MOF) nanosheets is proposed, which is fabricated by simple bottom-up synthesis method. Furthermore, environmentally friendly, renewable and abundant biomass phytic acid (PA) is modified on the surface of Co-MOF nanosheets, which releases free protons being capable of etching the framework of MOF to improve the hydrophilicity and conductivity of MOF. Compared with Co-MOF-based sensor, the Co-MOF@PA-based sensor exhibits significantly enhanced sensitivity and broadened response range within 23-95% relative humidity (RH). The humidity sensor has an excellent humidity sensing response over 2 x 103. The Co-MOF@PA-based sensor shows good flexibility and humidity sensing properties, endowing it with multifunctional applications in real-time facial respiration monitoring, skin humidity perception, cosmetic moisturizing evaluation and fruit freshness testing. Four respiration patterns, including slow breath, deep breath, normal breath and fast breath are wirelessly monitored in real time by Co-MOF@PA-based sensor and recorded by mobile phone software. The research work presents potential applications in human-machine interactions (HMI) devices in future. (c) 2021 Elsevier Inc. All rights reserved.
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