4.6 Article

Celgard/PIM-1 proton conducting composite membrane with reduced vanadium permeability

期刊

JOURNAL OF APPLIED POLYMER SCIENCE
卷 139, 期 16, 页码 -

出版社

WILEY
DOI: 10.1002/app.51985

关键词

batteries and fuel cells; coatings; electrochemistry; membranes

资金

  1. Russian Science Foundation [21-13-00143]
  2. Russian Science Foundation [21-13-00143] Funding Source: Russian Science Foundation

向作者/读者索取更多资源

In this study, novel composite Celgard-based films coated with PIM-1 were proposed for improving the performance of vanadium redox flow batteries (VRB) membranes. The deposited PIM-1 effectively reduced the pores diameter and influenced the transport properties of the composite film. The composite film showed enhanced ion selectivity and proton conductivity in aqueous VRB applications.
Renewable energy systems need efficient and cheap storage devices and vanadium redox flow batteries (VRB) may become one of them. However, better performance of VRB membranes yet should be achieved. Novel composite Celgard-based films coated with PIM-1 for aqueous electrolyte VRB applications are presented. Two types of the composites with different PIM-1 loadings are obtained. Their properties are studied and compared with the original Celgard films. The deposited PIM-1 forms a smooth layer on the outer Celgard surface and penetrates inside the porous matrix, thus significantly reducing the pores diameter and affecting the transport properties of the composite film. The nanoporous structure of PIM-1 permits size-screening of H3O+/hydrated vanadium ions when used in aqueous vanadium redox flow batteries applications, which allows to tailor the membrane permeability for the two types of ions and, therefore, to increase its selectivity from 4.3 x 10(6) to 1.3 x 10(7) mS min cm(-3), while maintaining high proton conductivity.

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