期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 891, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2021.161910
关键词
Perovskite solar cell; Cobalt ions doping; Magnetic field action; Stability; Efficiency
资金
- National Natural Science Foundation of China [21471140, 21101143]
The performance of CH3NH3PbI3 film was improved through Co2+ doping and magnetic field action, leading to enhanced stability and efficiency of the solar cells. This study proposed a novel theory for the influence of magnetic field action on perovskite solar cells doped with magnetic ions, offering a new idea for preparing cells with improved performance.
To improve the cell performance, CH3NH3PbI3 film prepared via a two-step method in air was modified by Co2+ doping and magnetic field action. Effects of Co2+ doping and magnetic field strength on film properties and cell performance were investigated. Possible influence mechanisms of Co2+ doping and magnetic field strength on perovskite structure, film properties and cell performance were studied. Results show that Pb in CH3NH3PbI3 was partially replaced by 10% Co, and Co2+ doped device exhibits ameliorative stabilities and efficiency compared with undoped one due to the more stable [Pb(Co)I-6](4-) octahedron structure and the suppression of ion migration, respectively. Then, weak magnetic field action furtherly improves stability and efficiency of CH3NH3Pb0.9Co0.1I3 based cell by furtherly stabilizing [Pb(Co)I-6](4)(-) octahedron structure and inhibiting ion migration, separately. This work has proposed a novel theory for magnetic field action in-fluencing the performance of magnetic ions doped perovskite solar cells and offered a new idea for pre-paring cells with improved performance, which is helpful to facilitate the commercialization of perovskite solar cells. (C) 2021 Elsevier B.V. All rights reserved.
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