4.7 Article

Fe-F Co-doped NaTi2(PO4)3/C anode material for high performance and long-life aqueous Li-ion battery

期刊

JOURNAL OF ALLOYS AND COMPOUNDS
卷 885, 期 -, 页码 -

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2021.161007

关键词

Aqueous lithium-ion battery; NaTi2(PO4)(3); Fe-F co-doping; Carbon coating

资金

  1. Recruitment Program of Global Experts
  2. Hundred-Talent Project of Fujian
  3. Fuzhou University

向作者/读者索取更多资源

The performance of NTP anode material for ALIBs was improved by carbon coating and Fe-F co-doping, with further enhancements achieved by using stainless steel as a gasket. The NTP-Fe-0.1-F-0.1/C material showed outstanding electrochemical properties and long cycling lifetime, attributed to enhanced structural stability and electron/Li+ ion transfer kinetics.
NASICON-type NaTi2(PO4)(3) (NTP) with stable 3D framework exhibits great application prospect as anode materials for aqueous lithium ion battery (ALIB). However, the low electrical conductivity of NTP adversely affects its rate and cycling performance. Surface coating and lattice doping are considered to be effective means to improve the performance of the material. Herein, carbon coated and Fe-F co-doped NTP anode materials were synthesized for ALIBs. It is found that the LiMn2O4 parallel to NTP-Fe-0.1-F-0.1/C full cell delivers a high discharge specific capacity of 112.8, 103.2 and 96.2 mAh g(-1) at 0.5, 5 and 10 C, respectively, in the voltage range of 0.5-1.9 V when Ni foam is used as gasket for the cell assembly. The performances of the cell especially the cycling lifetime at high charge-discharge rates are further improved using electrochemically stable stainless steel as gasket. A high coulombic efficiency of 100% and a low capacity decay of only 0.8% at 5 C and 14.9% at 10 C are achieved even after 2000 cycles of charge-discharge test. This is the most stable NTP-based ALIBs reported in the literature. The outstanding electrochemical property and the long cycling lifetime of the NTP-Fe-0.1-F-0.1/C material is due to the enhanced structural stability and electron/Li+ ion transfer kinetics. (C) 2021 Elsevier B.V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据