Superparamagnetic contributions, optical band gap tuning and dominant interfacial resistive mechanisms in ferrites nanostructures

Nanocrystalline Ni-Zn ferrite nanoparticles (NPs) NixZn1-xFe2O4 have been synthesized followed by detailed analysis of compositional effects on morphology, crystalline phase formation, lattice constant, crystallite size, magnetic, optical and dielectric properties describing the underlying physics as well. Cubic spinel structure with (311) preferred orientation and switching trend in crystallite size variation with gradual decrease in lattice parameter (from 8.377 to 8.323 angstrom) with the increase in nickel content has been observed through calculations. The magnetic behavior of NPs has been investigated at lower temperatures up to 5 K illustrating significantly improved magnetic parameters including M-s = 36.8 emu/g, M-r = 3.61 emu/g, SQ = M-r/M-s = 0.1028, H-c = 115.33 Oe, mu(B) = 1.5664 emu, and K-1 = 2122.18 erg/g. This enhancement has been found possibly due to less thermal fluctuations and significant superparamagnetic contributions from the very small fine nanoparticles being in blocking state owing to such a cool environment. Optical band gap for both direct (1.74-1.39 eV) and indirect (1.25-1.16 eV) transitions shows decreasing trend with the increase in Ni contents probably due to the redistribution of Ni or Zn contents from octahedral to tetrahedral site. Dielectric constant (real and imaginary) and tangent loss decreased with the increase of frequency, this refers to the Maxwell-Wagner type of polarization in the material in accordance with Koop's theory, however, a switching is observed at the stoichiometric ratio of x = 0.25 and 0.75. The impedance (Z') has maximum value 5539 k Omega at x = 0.75 and a minimum value 682 k Omega at x = 1.0. The Nyquist plot pointed out the contribution of grain boundaries, however the contribution varies with the stoichiometric ratio x. The Cole-Cole plot confirms the contribution of grains in the material for all value of x. (C) 2021 Elsevier B.V. All rights reserved.

Automated summary

Nanocrystalline Ni-Zn ferrite nanoparticles NixZn1-xFe2O4 were synthesized and their properties were analyzed. Increasing nickel content led to changes in crystalline structure, magnetic behavior, and optical and dielectric properties of the nanoparticles.