期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 895, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2021.162607
关键词
SnO2; MoO3; Solid solution; Lithium storage; Nanocomposites
资金
- National Natural Science Foundation of China [51804092]
- Joint Foundation of Taizhou City, Zhejiang Provincial Natural Science Foundation of China [TY21E020009]
- Fundamental Research Funds of Zhejiang Sci-Tech University
SnO2/SnxMo1-xO3-x solid solution-based nanocomposites were prepared via hydrothermal and annealing processes, demonstrating enhanced electrochemical performance for lithium storage applications. The ionic structures in the nanocomposites contribute to excellent cycling stability and high-rate performance.
SnO2/SnxMo1-xO3-x solid solution-based nanocomposites have been prepared via a two-step hydrothermal and following annealing processes. At a Sn/Mo molar ratio of 1:2 (the Sn/Mo = 1:2), a single-phase SnxMo1-xO3-x with ionic flake-like structure can be obtained; while, a SnO2/SnxMo1-xO3-x solid solution nanocomposite can be obtained at a Sn/Mo molar ratio of 1:1 (the Sn/Mo = 1:1), which combines with iconic sphere and flake-like structure. Then, electrochemical properties are systematically studied with pure SnO2 and pure MoO3 comparisons as anodes for LIBs. The after cycled Sn/Mo = 1:1 electrode could contain three phases of metallic Sn, MoO2 and an amorphous Sn-Mo oxides, which provide a general synergistic effect to enhance the surface charge contribution, reduce the charge transfer resistance and increase the reaction kinetics. Specifically, the Sn/Mo = 1:1 electrode exhibits a high initial coulombic efficiency of 73.5% with an excellent reversible lithium storage capacity of 735 mAh g(-1) at a current density of 0.4 A g(-1) after 500 cycles, and a high-rate performance with a specific capacity of 337 mAh g(-1) can be obtained at current density of 4 A g(-1). This work could provide some inspirations to design solid solution based nanocomposite with a general synergistic effect to enhance the electrochemical performance for lithium storage application. (C) 2021 Elsevier B.V. All rights reserved.
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