期刊
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
卷 22, 期 21, 页码 -出版社
MDPI
DOI: 10.3390/ijms222111856
关键词
biobased furans; renewable building blocks; plant biomass; Diels-Alder cycloaddition; selectivity; sustainable chemistry; biorefining
资金
- Russian Science Foundation [17-13-01176-p]
- Russian Science Foundation [20-13-18006] Funding Source: Russian Science Foundation
The recent trend towards green and sustainable chemistry has led to the increased use of renewable carbon sources. The Diels-Alder reaction plays a significant role in renewable resources chemistry, providing an efficient pathway for the production of low molecular weight products. Diels-Alder cycloaddition of furanic dienes with various dienophiles exemplifies a green process with 100% atom economy and reasonable E-factor.
A recent strong trend toward green and sustainable chemistry has promoted the intensive use of renewable carbon sources for the production of polymers, biofuels, chemicals, monomers and other valuable products. The Diels-Alder reaction is of great importance in the chemistry of renewable resources and provides an atom-economic pathway for fine chemical synthesis and for the production of materials. The biobased furans furfural and 5-(hydroxymethyl)furfural, which can be easily obtained from the carbohydrate part of plant biomass, were recognized as platform chemicals that will help to replace the existing oil-based refining to biorefining. Diels-Alder cycloaddition of furanic dienes with various dienophiles represents the ideal example of a green process characterized by a 100% atom economy and a reasonable E-factor. In this review, we first summarize the literature data on the regio- and diastereoselectivity of intermolecular Diels-Alder reactions of furfural derivatives with alkenes with the aim of establishing the current progress in the efficient production of practically important low-molecular-weight products. The information provided here will be useful and relevant to scientists in many fields, including medical and pharmaceutical research, polymer development and materials science.
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