4.7 Article

High-performing proton-conducting solid oxide fuel cells with triple-conducting cathode of Pr0.5Ba0.5(Co0.7Fe0.3)O3-δ tailored with W

期刊

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 47, 期 3, 页码 1947-1953

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2021.10.145

关键词

Cathode; Proton migration; Solid oxide electrolysis cells; Density functional theory

资金

  1. National Natural Science Foundation of China [11875164]
  2. Joint Open Fund of Jiangsu Collaborative Innovation Center for Ecological Building Material and Environmental Protection Equipments and Key Laboratory for Advanced Technology in Environ-mental Protection of Jiangsu Province [114269115]
  3. Natural Science Foundation of the Higher Education In-stitutions of Jiangsu Province [18KJA430017]

向作者/读者索取更多资源

In this study, a series of W doped Pr0.5Ba0.5(Co0.7Fe0.3)O3-delta (PBCF) were prepared and characterized as cathodes for proton-conducting solid oxide fuel cell (H-SOFC). The enhancement of proton migration and formation ability through W doping significantly increases the cell performance, which was further verified by density functional theory (DFT) simulation, indicating that high valence element doping can be a potential approach for cathode design.
A series of W doped Pr0.5Ba0.5(Co0.7Fe0.3)O3-delta (PBCF) are prepared and characterized as cathodes for proton-conducting solid oxide fuel cell (H-SOFC). The enhancement of proton migration and formation ability through W doping significantly increases the cell performance and it is further verified by the density functional theory (DFT) simulation, presenting the high valence element doping can be a potential approach for the design of cathode. (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

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