期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 47, 期 7, 页码 4814-4826出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2021.11.084
关键词
PEMFC; HTPEMFC; Model parameter estimation; Genetic algorithm
This paper proposes a novel approach to parameterize high temperature exchange membrane fuel cells (HTPEMFC) by combining computational simulation tools and genetic algorithms. The method effectively identifies electrochemical parameters of three-dimensional fuel cell models and decouples the fluid dynamic resolution from the electrochemistry one. The results demonstrate that a unique set of electrochemical parameters can be identified from a set of measured operating conditions that fits the 3D model to the target polarisation curve.
This paper develops a novel approach to the parameterisation of high temperature exchange membrane fuel cells (HTPEMFC) with limited and non-invasive measurements. The proposed method allows an effective identification of electrochemical parameters for three-dimensional fuel cell models by combining computational simulation tools and genetic algorithms. To avoid each evaluation undertaken by the optimisation method involving a complete computational simulation of the 3D model, a strategy has been designed that, thanks to an iterative process, makes it possible to decouple the fluid dynamic resolution from the electrochemistry one. Two electrochemical models have been incorporated into these tools to describe the behaviour of the catalyst layer, Butler-Volmer and spherical aggregate. For each one, a case study has been carried out to validate the results by comparing them with empirical data in the first model and with data generated by numerical simulation in the second. Results show that, from a set of measured operating conditions, it is possible to identify a unique set of electrochemical parameters that fits the 3D model to the target polarisation curve. The extension of this framework can be used to systematically estimate any model parameter in order to reduce the uncertainty in 3D simulation predictions. (c) 2021 The Author(s). Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC. This is an open access article under the CC BY license (http://creativecommons.org/ licenses/by/4.0/).
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