期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 47, 期 2, 页码 1048-1062出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2021.10.096
关键词
Mg/Ni layered material; Composite structure; Accumulative fold-forging (AFF); Microstructure; Hydrogen storage
An advanced SPD method called accumulative fold-forging was used to produce layered nanostructured MgNi alloys with superior hydrogen storage capacity. Adjusting the structure can control hydrogen uptake and release characteristics, while refining the grain structure to the nano-scale range can further enhance hydrogen absorption capacity.
An advanced and newly developed severe plastic deformation (SPD) method called accumulative fold-forging (AFF) was applied to produce layered nanostructured MgNi alloys exhibiting superior hydrogen storage capacity. Microstructural developments and storage properties were characterized in depth to correlate the structure and performance of this advanced material. The enhanced hydrogen storage performance of the magnesium-based layered composite material was investigated in comparison to the pristine state by conducting hydrogenation and dehydrogenation testing. It was also shown that the hydrogen uptake and release characteristics can be controlled by adjusting the layered structure or the Mg: Ni stoichiometry ratio. Refining the grain structure of the magnesium alloy down to the nano-scale range (similar to 400-900 nm) by applying high cycles AFF consolidation to promote creation of multi-million nanometric interfaces led to superior storage performance with a remarkable hydrogen absorption capacity of up to similar to 1.425 wt%. X-ray diffraction (XRD) analysis of the hydrogenated products revealed the formation of MgH2 that indicates the dominance of the magnesium matrix for controlling the hydrogen storage behavior of the layered Mg/Ni composite material. Finally, the relationship between the directional hydrogen storage behavior and the induced structural features upon AFF treatment were also established using quantitative characterization and analytical tools. (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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