4.5 Article

Platinum(II), palladium(II), and nickel(II) complexes of bisthiourea ligands

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Summary: The versatile nature and facile construction of mixed donor acylthiourea ligands have led to the design and synthesis of new photo-active, macrocyclic, and heteroleptic complexes in recent years. There has been significant progress in the preparation and study of trans-[M(L-kappa S,O)(2)] complexes, particularly in relation to their photo-active behavior and trans -> cis isomerism kinetics. Additionally, there is renewed interest in using bipodal acylthiourea analogues as building blocks in the synthesis of new coordination-driven metallacycles and metallacages.

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