期刊
INORGANIC CHEMISTRY
卷 60, 期 20, 页码 15118-15123出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.1c02494
关键词
-
资金
- Ministry of Science and Technology of Taiwan [MOST 109-2113-M-110-004]
Treatment of PtMe3I with [R-PNP]Li or H[R-PNP] in tetrahydrofuran at room temperature leads to fac-[R-PNP]PtMe3, which upon thermolysis in benzene generates mer-[R-PNP]PtMe3, representing the first meridional trialkylplatinum(IV) derivatives.
Treatment of PtMe3I in tetrahydrofuran with either in situ prepared [R-PNP]Li ([R-PNP](-) = [(R2P-o-C6H4)(2)N](-); R = Ph, iPr) or H[R-PNP] in the presence of triethylamine at room temperature affords quantitatively fac-[R-PNP]PtMe3. Thermolysis of fac-[R-PNP]PtMe3 in benzene solutions generates mer-[R-PNP]PtMe3 and ultimately [R-PNP]PtMe and ethane. Complexes mer-[R-PNP]PtMe3 represent the first meridional trialkylplatinum(IV) derivatives to date.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据