期刊
INORGANIC CHEMISTRY
卷 60, 期 24, 页码 18854-18858出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.1c02584
关键词
-
Three novel palladium(II) mixed-ligand complexes were synthesized and fully characterized in this study, showing different coordination modes of the ligand HL. The complexes were characterized using various techniques, with complex 3 further characterized by single-crystal X-ray diffraction.
Three novel palladium(II) mixed-ligand complexes of N-(benzothiazol-2-yl)benzamide (HL) and 1,2-bis(diphenylphosphino)ethane (dppe), [Pd(HL)(dppe)]Cl-2 (1), [Pd(L)(dppe)]Cl (2), and [Pd(L)(2)(dppe)] (3), were synthesized and fully characterized using Fourier transform infrared, H-1, C-13, and P-31 NMR, and molar conductivity measurements. Complex 3 was characterized by single-crystal X-ray diffraction. The ligand HL showed three different coordination modes: a neutral bidentate chelate bound through the endocyclic nitrogen and exocyclic oxygen atoms in 1, a negatively charged L bound as a bidentate chelate through the endocyclic nitrogen and negatively charged exocyclic oxygen atoms in 2, and a monodentate bound through the negatively charged endocyclic nitrogen atom in 3.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据