Investigations on the Synthesis, Crystal Structure, Linear- and Nonlinear-Optical Properties of the Zinc Germanate Rb2ZnGe2O6

A quaternary nonlinear-optical (NLO) zinc germanate, Rb2ZnGe2O6 (RZGO), was prepared from its stoichiometric melts, which belongs to the noncentrosymmetric space group C222(1) (No. 20) and features a 3D framework formed by GeO4 tetrahedra, ZnO4 tetrahedra, and Rb+ cations filling into the void space. RZGO displays a good phase-matchable second-harmonic-generation (SHG) intensity similar to that of KH2PO4. The UV cutoff edge for RZGO was found to be approximately 0.37 mu m with a broad optical band gap of 3.22 eV, indicating a large laser-induced damage threshold. Further characterizations suggested that this compound displays an excellent thermal stability (1014 degrees C) and melts congruently. Besides, theoretical analysis was also implemented to investigate the electronic structures and effective NLO coefficients as well as the origin of the observed SHG response for RZGO. The present study can enrich the diversity of acentric germanate structures and pave the way for the synthesis of new NLO compounds.

Automated summary

RZGO is a quaternary nonlinear-optical zinc germanate with good SHG intensity and a wide optical band gap, suitable for second-harmonic-generation. The compound also demonstrates excellent thermal stability and congruent melting behavior.