Unsaturated Sulfur Crown Ethers Can Extract Mercury(II) and Show Promise for Future Copernicium(II) Studies: A Combined Experimental and Computational Study

The unsaturated hexathia-18-crown-6 (UHT18C6) molecule was investigated for the extraction of Hg(II) in HCl and HNO3 media. This extractant can be directly compared to the recently studied saturated hexathia-18-crown-6 (HT18C6). The default conformation of the S lone pairs in UHT18C6 is endodentate, where the pocket of the charge density, according to the crystal structures, is oriented toward the center of the ring, which should allow better extraction for Hg(II) compared to the exodentate HT18C6. Batch study experiments showed that Hg(II) had better extraction at low acid molarity (ca. 99% in HCl and ca. 95% in HNO3), while almost no extraction was observed above 0.4 M HCl and 4 M HNO3 (<5%). Speciation studies were conducted with the goal of delineating a plausible extraction mechanism. Density functional theory calculations including relativistic effects were carried out on both Hg(II)-encapsulated HT18C6 and UHT18C6 complexes to shed light on the binding strength and the nature of bonding. Our calculations offer insights into the extraction mechanism. In addition to Hg(II), calculations were performed on the hypothetical divalent Cn(II) ion, and showed that HT18C6 and UHT18C6 could extract Cn(II). Finally, the extraction kinetics were explored to assess whether this crown can extract the short-lived Cn(II) species in a future online experiment.

Automated summary

In this study, the unsaturated hexathia-18-crown-6 (UHT18C6) molecule was investigated for its extraction efficiency of Hg(II) in HCl and HNO3 media, compared to the saturated hexathia-18-crown-6 (HT18C6). Batch experiments showed that Hg(II) had better extraction at low acid molarity, but almost no extraction was observed at high acid concentrations. Speciation studies and density functional theory calculations were also conducted to understand the extraction mechanism and the bonding nature. The results indicated that UHT18C6 can potentially extract both Hg(II) and Cn(II), and the extraction kinetics were explored for future applications with short-lived Cn(II) species.