Outstanding Stability and Enhanced Catalytic Activity for Toluene Oxidation by Si-O-Mn Interaction over MnOx/SiO2

Emissions of volatile organic compounds (VOCs) have caused serious damage to the environment and public health. Catalytic combustion is an efficient technology for VOC elimination. In this study, porous silica supported amorphous MnOx was constructed. It presented excellent stability and high activity for toluene combustion, even under the high humidity (T-90 = 218 degrees C). Compared with bulk amorphous MnOx, the catalytic activity has been improved by more than 11 times. The various characterizations and quantum chemical calculation results suggested that the Si-O-Mn hybridization induced weakening of the Mn-O bond strength and electron transfer from the catalyst to surface oxygen species. A promoting effect of the Si-O-Mn interaction on the spillover of active O species was proposed which enhanced the catalytic activity. In-situ DRIFTS and XPS analytical results determined the reaction mechanism and revealed that both O(lat)t and O-surf participate in the catalytic oxidation of toluene. The problem of the poor thermal stability of amorphous MnOx has been solved in this work. This work provides a convenient and effective method to prepare efficient catalysts with high activity and good thermal stability for VOC catalytic combustion.

Automated summary

A porous silica supported amorphous MnOx catalyst with excellent stability and high activity for catalytic combustion of volatile organic compounds (VOCs) has been successfully constructed. The Si-O-Mn hybridization was found to enhance the activity by promoting the spillover of active oxygen species.