期刊
HELVETICA CHIMICA ACTA
卷 105, 期 3, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/hlca.202100225
关键词
alkyne cycloisomerization; chirality; helical structures; redox properties; thiahelicenes; thiophene derivatives
资金
- Czech Science Foundation [20-23566S]
- Institute of Organic Chemistry and Biochemistry, Czech Academy of Sciences [RVO: 61388963]
A series of inherently chiral di- and tetrathiahelicenes/dithiophenohelicenes were synthesized and their structural and physicochemical properties were studied and compared with other related compounds.
A series of inherently chiral (di)thiahelicenes/dithiophenohelicenes containing 5, 6, 9 or 11 (hetero)cycles in their helical backbone with thiophene subunit(s) embedded in it or annulated to its periphery were uniformly synthesized by intramolecular alkyne [2+2+2] cycloisomerization. Their structural, chemical and physicochemical properties such as crystal packing, oxidation, barrier to racemization, spontaneous thin film transformation or electrochemical behavior were studied and compared with the respective properties of the parent all-carbon helicenes and dibenzohelicenes.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据