期刊
GREEN CHEMISTRY
卷 24, 期 5, 页码 2036-2043出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1gc03850h
关键词
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资金
- MICIU/AEI/FEDER [RTI2018-098233-B-C22, RTI2018-098237-B-C22]
- Universitat Jaume I [UJI-B2019-40, UJI-B2018-23]
- Generalitat Valenciana [ACIF/2019/100]
- MINECO [FPU15/03011]
A simple, safe, and robust system for the continuous, in situ, and on-demand generation of highly pure hydrogen under mild conditions is reported. The system utilizes a catalyst supported on graphene for the dehydrogenative coupling reaction, and the generated hydrogen can be used for further hydrogenation reactions.
A simple, safe and robust system for the continuous, in situ and on demand generation of hydrogen under mild conditions is reported. A device formed by a packed bed reactor containing a ruthenium N-heterocyclic carbene complex [Ru(arene)(Cl)(2)(NHC)] supported onto graphene (NHC-Ru-rGO) and a liquid-gas separator allows the continuous generation of hydrogen produced by the dehydrogenative coupling of silanes and alcohols under mild and safe conditions. The highly pure hydrogen generated can be used for further hydrogenation reactions under both batch and continuous flow conditions.
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