4.7 Article

Consistent mineral-associated organic carbon chemistry with variable erosion rates in a mountainous landscape

期刊

GEODERMA
卷 405, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.geoderma.2021.115448

关键词

Mineral-associated organic carbon; Erosion; X-ray absorption near-edge fine structure spectroscopy (XANES); Radiocarbon (C-14); Soil organic carbon; Synchrotron

资金

  1. Canada Foundation for Innovation
  2. Natural Sciences and Engineering Research Council of Canada
  3. University of Saskatchewan
  4. Government of Saskatchewan
  5. Western Economic Diversification Canada
  6. National Research Council Canada
  7. Canadian Institutes of Health Research
  8. National Natural Science Foundation of China [42077063]
  9. National Science Foundation [EAR1253198]

向作者/读者索取更多资源

In steep mountainous landscapes constrained by erosion, the longevity of soil organic carbon is largely independent of organic matter chemistry.
Interactions between organic carbon (OC) and minerals represent a critical mechanism for stabilizing organic matter in soils. Because both mineral weathering and plant productivity are negatively affected by soil erosion, mineral-associated organic carbon (MOC) chemistry is also expected to vary with erosion intensity. Here we show that MOC chemistry, determined by carbon X-ray absorption near-edge fine structure spectroscopy (XANES), exhibits little difference across a large (10-fold) gradient in erosion-derived soil turnover times. Mineral-associated OC chemistry further fails to explain the variation in radiocarbon-based MOC turnover times. Our results suggest that soil OC longevity is largely independent of organic matter chemistry in steep mountainous landscapes where soil development is constrained by erosion.

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