4.7 Article

Performance and mechanism of MnOx/γ-Al2O3 for low-temperature NO catalytic oxidation with O3/NO ratio of 0.5

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Effective toluene oxidation under ozone over mesoporous MnOx/γ-Al2O3 catalyst prepared by solvent deficient method: Effect of Mn precursors on catalytic activity

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Summary: The study systematically examined the role of manganese precursors in mesoporous MnOx/gamma-Al2O3 catalysts for toluene oxidation under ozone at ambient temperature, with MnOx/Al2O3(C) showing superior performance in toluene removal and ozone decomposition. The superior performance of MnOx/Al2O3(C) is attributed to the highly dispersed MnOx facilitating ozone decomposition and the vital role of toluene adsorption over the acid support. The study highlights the importance of properties such as Mn3+/Mn4+ ratio, acidic sites, and particle size in the catalytic performance.

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