期刊
FUEL
卷 305, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2021.121513
关键词
Biomass; Hydrothermal treatment; Chemical structure; Pyrolysis; Wood vinegar
资金
- National Natural Science Foundation of China [51761125011]
- National Key Research and Development Project of China [2017YFB0602102]
The comprehensive evolution of biomass structure through hydrothermal treatment can lead to the production of valuable products. The study found that hydrothermal treatment affects the chemical structure of cotton stalks, increasing carbon content and removing alkali metals. Different components decompose at different temperatures and times, with hydrothermal temperature having a more significant impact on the chemical structure than residence time. Additionally, the hydrothermally treated cotton stalks exhibit hydrophilic surface characteristics and can be used to produce wood vinegar.
Hydrothermal treatment can arouse the comprehensive evolution of biomass structure, which broadens the horizons for the development and optimization of terminal products from biomass valorization. The dynamic evolution of the chemical structure of cotton stalk during hydrothermal treatment of 180-280 degrees C within 0-120 min was comprehensively studied by various ex-situ characterization techniques, as well as its basic properties. The feasibility of wood vinegar preparation from the hydrothermally treated cotton stalk (HTCS) was evaluated by pyrolysis at 350 degrees C. The carbon content of the HTCS samples increase from 44.68% to 65.96% with increasing hydrothermal temperature from 180 degrees C to 280 degrees C without retention, and from 53.86% to 57.95% at 230 degrees C with increasing residence time from 0 min to 120 min, respectively. Meanwhile, the oxygen content of the HTCS samples decrease significantly with intensifying hydrothermal treatment. The alkali metals in the HTCS samples are removed apparently with increasing hydrothermal severity. Hydrothermal temperature has a more significant effect on the chemical structure than residence time. Hemicellulose was decomposed at 180-200 degrees C, and lignin decomposition occurred above 200 degrees C, which was intensified at 260-280 degrees C without retention and at 230 degrees C within 30-60 min. Amorphous cellulose was decomposed at 200-230 degrees C, and the crystalline cellulose was mainly decomposed at 230-280 degrees C and at 230 degrees C within 0-30 and 60-120 min, respectively. The HTCS samples show the hydrophilic surface characteristic due to a deal of residual surface oxygen-containing groups. The growth of the aromatic system could be promoted under the hydrothermal treatment below 260 degrees C. The hydrothermally treated cotton stalk at 230 degrees C without retention could be used to prepare wood vinegar with the abundant phenols and ketones through pyrolysis at 350 degrees C. Overall, the study will provide insight into the preparation of diverse value-added products and guidance to the fabrication of advanced functional materials from hydrothermally treated biomass.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据