Study of rapeseed oil gelation induced by commercial monoglycerides using a chemometric approach

Commercial oleogelators rich in monoglycerides (MGs) are complex mixtures of acylglycerides with variable gelling properties, depending on the oil used and their concentration. In this study we developed a chemometric approach to identify the key parameters involved in gelling process. Analytical parameters have been defined, using GC and NMR analysis to identify fatty acids and acylglycerides composing the mixtures. Specific acylglyceride families and compound ratios were calculated to streamline the analytical results. To determine the key analytical parameters, artificial neural networks were used in a QSPR study related to the gelling properties measured by rheology through oscillatory experiments. At low oleogelator concentrations, the MGs especially rich in C16:0 and the ratio of specific isomers both have a positive influence on G'. For high oleogelator concentrations, C18:0-rich acylglycerides and unsaturated/saturated fatty acid ratios have a positive influence on G'. Conversely, at low concentrations, C18:0-rich acylglycerides show a lesser effect on G'

Automated summary

Commercial oleogelators containing monoglycerides (MGs) are complex mixtures with gelling properties affected by the oil used and concentration. A chemometric approach was developed to identify key parameters in the gelling process. Results showed that specific isomers and unsaturated/saturated fatty acid ratios have different effects on G' at low and high oleogelator concentrations.